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排序方式: 共有298条查询结果,搜索用时 15 毫秒
61.
A. Napier J. Schneps T.Y. Chen E.W. Jenkins K-W. Lai J. Le Britton Y.C. Lin A.E. Pifer H.C. Fenker D.R. Green J.R. Albright J.H. Goldman S.L. Hagopian J.E. Lannutti J.E. Piper C.C. Chang T.C. Davis R.N. Diamond W.P. Trower 《Physics letters. [Part B]》1984,149(6):514-518
K1±(892) production is studied in the reaction π?N → KS0KS0 + X where X includes up to five observed charged particles. An excess of K1? over K1+ is observed for Feynman-x > 0.1. The ratio of K1+ to K1? decreases with x as predicted by QCD counting rules. KS0 and K1 production are compared to recent D and D1 data from other experiments. 相似文献
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M. M. Britton P. T. Callaghan M. L. Kilfoil R. W. Mair K. M. Owens 《Applied magnetic resonance》1998,15(3-4):287-301
We describe several different rheometric devices for use within the nuclear-magnetic-resonance probe of a standard widebore microimaging system. These include both vertical and horizontal Couette cells and the cone- and -plate cell, which produce shearing flows, and the four-roll mill and the opposed-jet (cross-flow junction) cells which produce extensional flow. We demonstrate that velocity images can be obtained for each and that detailed information about local shear and extension rates can be extracted. These systems have considerable potential for use in the study of non-Newtonian viscosity, and of molecular ordering under shear or extension. 相似文献
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A slow positron lifetime study of the annealing behaviour of an amorphous silicon layer grown by MBE
J. Störmer P. Willutzki D. T. Britton G. Kögel W. Triftshäuser W. Kiunke F. Wittmann I. Eisele 《Applied Physics A: Materials Science & Processing》1995,61(1):71-74
We have studied MBE grown amorphous silicon, which was recrystallized at different temperatures for one hour, with a pulsed positron beam. A positron lifetime of 538±10 ps in the as-grown state is attributed to microvoids containing at least 10 vacancies. An incompletely recrystallized sample annealed at 500°C shows an additional long lifetime from ortho-positronium (o-Ps) pick-off annihilation. The o-Ps component disappears for samples, recrystallized at 700°C and above, and the defect lifetime steadily decreases with higher annealing temperature until a value of 310 ps is reached for the layer annealed at 1200°C. This value is explained by positron trapping at dislocations or small vacancy defects stabilized by dislocations or impurities.Paper presented at the 132nd WE-Heraeus-Seminar on Positron Studies of Semiconductor Defects, Halle, Germany, 29 August to 2 September 1994 相似文献
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Weiwu Ren Marco Farren-Dai Natalia Sannikova Katarzyna
widerek Yang Wang Oluwafemi Akintola Robert Britton Vicent Moliner Andrew J. Bennet 《Chemical science》2020,11(38):10488
Carbasugars are structural mimics of naturally occurring carbohydrates that can interact with and inhibit enzymes involved in carbohydrate processing. In particular, carbasugars have attracted attention as inhibitors of glycoside hydrolases (GHs) and as therapeutic leads in several disease areas. However, it is unclear how the carbasugars are recognized and processed by GHs. Here, we report the synthesis of three carbasugar isotopologues and provide a detailed transition state (TS) analysis for the formation of the initial GH-carbasugar covalent intermediate, as well as for hydrolysis of this intermediate, using a combination of experimentally measured kinetic isotope effects and hybrid QM/MM calculations. We find that the α-galactosidase from Thermotoga maritima effectively stabilizes TS charge development on a remote C5-allylic center acting in concert with the reacting carbasugar, and catalysis proceeds via an exploded, or loose, SN2 transition state with no discrete enzyme-bound cationic intermediate. We conclude that, in complement to what we know about the TS structures of enzyme-natural substrate complexes, knowledge of the TS structures of enzymes reacting with non-natural carbasugar substrates shows that GHs can stabilize a wider range of positively charged TS structures than previously thought. Furthermore, this enhanced understanding will enable the design of new carbasugar GH transition state analogues to be used as, for example, chemical biology tools and pharmaceutical lead compounds.Positive charge stabilized on remote C5-allylic center with catalysis occurring via a loose SN2 transition state. 相似文献
68.
Margaret C. Etter Diana L. Parker Shiyamalie R. Ruberu Thomas W. Panunto Doyle Britton 《Journal of inclusion phenomena and macrocyclic chemistry》1990,8(4):395-407
During crystallization 1,3-cyclohexanedione self assembles into either hydrogen-bonded chains or hexameric rings depending on the solvent conditions. The hexameric rings, called cyclamers, are the subject of this paper. These unusual structures occlude benzene as a guest molecule. The structural and crystal chemical properties of these host-guest compounds are explored here with the use of crystal growth studies, X-ray powder patterns, and thermal analysis. The crystal structure of the benzene cyclamer of 5-methyl-1,3-cyclohexanedione is reported (hexagonal,a =b = 19.19(2)Å,c = 10.545(9)Å,R3,Z = 18,V = 3362(6)Å3; 717 unique reflections,R = 0.062). An analysis of the stereochemical implications of cyclic directionality in these cyclamers is also discussed.Alfred P. Sloan Foundation Fellow, 1989–1991. 相似文献
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